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pH imaging sensors
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Background
Scanning Chemical Microscope
Microscope Setup
pH Imaging Sensor
Analysis of Sample using pH Imaging
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Summary
Scanning Chemical Microscope

  • Electrochemical-Semiconductor Flat pH Sensor.
  • Multiple Points of pH Measurements.
  • Visualization of Localized pH Distribution.
    - 50 µm resolution
    - 0.01 pH sensitivity
    - 25 sec for 6.4 mm x 6.4 mm (1 sec for 10 mm)


Next, I would like to outline our Scanning Chemical Microscope. This microscope utilizes a flat pH sensor, which we call "pH imaging sensor", that can be made function as an array of point sensors based on an electrochemical-semiconductor principle when aided by the light illumination from the backside. Measured pH values at each measurement point are processed to be a pH image. So far, a resolution of 5µm with 0.01 pH sensitivity has been attained by this pH imaging technology. However, in practical application, pH imaging is made with 50 to 200µm resolution. The time required for obtaining a single pH image depends on the size of the measured area and resolution of the image. For example, a 6.4 mm by 6.4 mm image with a resolution of 100µm can be obtained in 25 sec. We can also measure just the liner profile once we have identified the regions of interest. In this case, a profile 1cm long can be obtained at a speed of 1cm/sec.

Moreover, the sensor can theoretically be made sensitive to chemical substances or ions other than protons for pH detection by modifying the sensing surface. This is why we refer to our microscope as a "Chemical Microscope". However, we have been involved in only the proton sensitive sensor so far. Since pH is one of the most important properties of a solution, imaging of the pH distribution has wide variety of application we regard.
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