Japan Worldwide
News & EventsInvestorsProcurementCompany HomeContactsSite MapJapanese
Products & Support Automotive Process & Environmental Medical-Diagnostics Semiconductor Scientific Applications
Measurement Types
Product List
 HOME >> The Story of Conductivity >> Chapter 1 - The Fundamentals
The Story of Conductivity
image

- Chapter 1 -
The Fundamentals
The History of Conductivity
Electricity and Ohm's Law
What is Conductivity ?
Ions in Water, and Conductivity
Strong Electrolytes, Weak Electrolytes
Temperature Compensation
Measuring Conductivity

- Chapter 2 -
Story of Water in Our Daily Lives
Pure Water
Acid Rain
Delicious Water
Hard Water, Soft Water
"Miyamizu"
Ice
River Water
Tropical Fish
Measurement of Soil
Acid Strength
The Story of the Salinometer
Application of Other Conductivity Meters

Chapter 1 - The Fundamentals


We have so far dealt with Ohm's law and conductivity in general, and hope you understand the concept. You may wonder, however, what it has to do with the measurement of the conductivity of water--the real question from the beginning. So, we are now going into the main subject.

So far, we have discussed the flow of electricity through an electric wire. A metal, such as in an electric wire, contains a great number of free electrons. These electrons pass electric current from one to the next, just like a line of people forming a bucket brigade. Such a metal is called a conductor.

The next subject involves what is called an ion conductor, basically ions in an electrolyte solution, which also affect the conducting of electricity.

We will now discuss some of the new terms that have come up. When a certain substance is dissolved in liquid--water in the case of Twin--and if the liquid thus obtained can conduct electricity, such a liquid is called an electrolyte solution, and the dissolved substance is called an electrolyte. And each corpuscle that carries electricity is called an ion (a Greek word meaning wanderer).

Common table salt (NaCl) is an electrolyte, and when this is dissolved in water to form salt water, it becomes sodium ions (Na+) and chlorine ions (Cl-), each of which is a corpuscle that conducts electricity.

Let's go back to conductivity. Conductivity is an index of how easy it is for electricity to flow. In water, it is the ions that pass electricity from one to the next. This means that the more Na+ and Cl- contained in water the more electricity is carried, and the higher the conductivity.

To sum up, if we know the conductivity of a sample of salt water, we can calculate just how salty the water is. (This is what happens in the salinity conversion to arrive at the value displayed by the Twin conductivity meter.)


Salinity (density of salt in salt water) and conductivity
Liquid temperature 25°C

NaCl density
(W / V) %
Conductivity
(mS / cm)
NaCl density
(W / V) %
Conductivity
(mS / cm)
0.1
2.0
1.1
19.2
0.2
3.9
1.2
20.8
0.3
5.7
1.3
22.4
0.4
7.5
1.4
24.0
0.5
9.2
1.5
25.6
0.6
10.9
1.6
27.1
0.7
12.6
1.7
28.6
0.8
14.3
1.8
30.1
0.9
16.0
1.9
31.6
1.0
17.6
2.0
33.0



You now understand that we can determine the salinity of salt water by knowing its conductivity. Some of you may wonder whether sugar water can also be measured. Unfortunately, a conductivity meter cannot tell you the density of sugar in water. Although sugar is soluble in water, it does not form ions, which means that it is not an electrolyte. Only when ions are produced in water can the density of the dissolved substance be calculated from conductivity measured using a conductivity meter.

Like a human, an electrolyte has a variety of properties. Electrolytes can be broadly divided into strong electrolytes and weak electrolytes. Let's spend some time on this subject.


Salt contains NaCl and KCl, which form electrolytes when dissolved in water, most of which become ions. The relationship between density and conductivity is nearly linear. As is seen in the diagram, however, unlike the low-density zone, the high-density zone does not show an increase in conductivity with a further increase in density. There comes a saturation point not unlike a traffic jam, where the ions act against each other, and this makes it hard for electricity to flow.


In a very low density zone, conductivity has a linear relationship with density, as is seen with organic acids. Acetic acid solution is a good example. However, as density increases, the rate of ionization decreases. In the high-density zone, only part of the electrolyte is ionized, and the overcrowding causes most of the potential ions to remain dissolved in water as molecules.




About mol/l (moles per liter): The mol (symbol for the SI unit mole) is one of the chemical units we use for expressing the measured quantity of a substance. The number of atoms or molecules in one mol of a substance is equal to the Avogadro constant, which has a value of 6.022 X 10. Therefore, the unit of density mol/l (moles per liter) indicates how much of a substance (in mol) is dissolved in 1 liter of a solution.


TOP
Copyright (C) 2008 HORIBA, Ltd. All rights reserved.

Copyright © 2008 HORIBA, Ltd. All rights reserved. The information shown on this document may be modified without notice. Refer to the original web page for update. The page was copied from:
 
Explore the future HORIBA